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Methanesulfonic acid detection limit

Record: 718


Category: Specifications
Product: SI-90
Sample:


Question
http://www.shodex.com/japanese/dc070518.html wants to know DL of methansulfonic acid

 
 

Answer
この分析系ではメタンスルホン酸は
25ppb程度は検出できると思います。

メタンスルホン酸のpKaは2くらいのようですので、ノンサプレッサも分析できると
思います。他の無機イオンが含まれていないのでしたら、NI-424のp-ヒドロキシ安
息香酸を使用した溶離液条件で可能だと思います。
しかし、検出感度はサプレッサよりはよくないと思われます。

 
 
Additional Comments
“In this analysis system, methanesulfonic acid is
I think it can detect around 25ppb.
Translation:
The pKa of methanesulfonic acid seems to be around 2, so non-suppressor can also be analyzed.
I think so. If no other inorganic ions are included, the p-hydroxyl base of NI-424
I think it is possible with the eluent conditions using zozoic acid.
However, the detection sensitivity seems to be lower than that of a suppressor.
“

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